Zinc Oxide/Moringa Oleifera Gum-Grafted L-Methionine-Functionalized Polyaniline Bionanocomposites for Water Purification

This study evaluates the preparation of novel ternary functional adsorbents based on polyaniline, zinc oxide nanoparticles, and moringa oleifera gum to produce zinc oxide/Moringa oleifera gum-grafted L-methionine-functionalized polyaniline bionanocomposites (ZM-g-Pani) and employed to sequestrate divalent metal ions (Cd2+, Hg2+ and Pb2+) from wastewater samples. The morphological and structural properties of ZM-g-Pani were exploited using FT-IR, FE-SEM/EDS, TEM, and XRD. FT-IR and FE-SEM studies show that the as prepared nanocomposite has an abundant number of reactive groups and a porous structure, thus demonstrating outstanding divalent metal cation removal. FT-IR study confirms that the attachment of L-methionine to polyaniline is facilitated by the C-S linkage. Both TEM and FE-SEM techniques confirmed the clustered granules of ZnO over the surface of polyaniline, which ultimately provided more surface area to adsorb metal ions. The study demonstrated that Cd2+, Hg2+ and Pb2+ ions could undergo physical sorption and chemisorption simultaneously during the adsorption process. The maximum adsorption capacity was 840.33, 497.51, and 497.51 mg/g for Cd2+, Hg2+, and Pb2+, respectively. The impact of co-existing ions, including NO3−, PO43−, SO42−, Cl−, Na+, Cu2+, and Al3+, showed that there were no notable alterations in the adsorption of the selected metal ions with ZM-g-Pani. ZM-g-Pani showed eight successive regeneration cycles for Cd2+, Hg2+, and Pb2+ with more than 85% removal efficiency.