Javascript must be enabled to continue!
Synthesis of Cyclobutanes by Lewis Acid‐Promoted Ketene‐Alkene [2+2] Cycloadditions
View through CrossRef
Abstract
When compared to thermally‐induced reactions, Lewis acid‐promoted variants give rise to increased yields for unactivated alkenes. The article describes the synthesis of cyclobutanes by Lewis acid‐promoted ketene‐alkene [2+2] cycloadditions.
Title: Synthesis of Cyclobutanes by Lewis Acid‐Promoted Ketene‐Alkene [2+2] Cycloadditions
Description:
Abstract
When compared to thermally‐induced reactions, Lewis acid‐promoted variants give rise to increased yields for unactivated alkenes.
The article describes the synthesis of cyclobutanes by Lewis acid‐promoted ketene‐alkene [2+2] cycloadditions.
Related Results
Total Synthesis of Gracilioether F: Development and Application of Lewis Acid Promoted Ketene–Alkene [2+2] Cycloadditions and Late‐Stage CH Oxidation
Total Synthesis of Gracilioether F: Development and Application of Lewis Acid Promoted Ketene–Alkene [2+2] Cycloadditions and Late‐Stage CH Oxidation
AbstractThe first synthesis of gracilioether F, a polyketide natural product with an unusual tricyclic core and five contiguous stereocenters, is described. Key steps of the synthe...
Alkene Reactions: The Dabdoub/Baroni Synthesis of ( ± )-Dihydroactinidiolide
Alkene Reactions: The Dabdoub/Baroni Synthesis of ( ± )-Dihydroactinidiolide
David B. Cordes of Pacific University reported (Tetrahedron Lett. 2009, 50, 1817) a simple combination of NaBH4 and Pd/C that reduced the alkene 1 to 2. This could be particularly ...
Reactions of Alkenes: The Usami Synthesis of (−)-Pericosine E
Reactions of Alkenes: The Usami Synthesis of (−)-Pericosine E
Dasheng Leow of the National Tsing Hua University used (Eur. J. Org. Chem. 2014, 7347) photolysis to activate the air oxidation of hydrazine to generate diimide, that then reduced ...
Acid Fracturing Technique for Carbonate Reservoirs Using Nitric Acid Powder
Acid Fracturing Technique for Carbonate Reservoirs Using Nitric Acid Powder
Abstract
The length of the etched fracture is rather limited utilizing traditional acid fracturing techniques, especially in a high-temperature carbonate reservoi...
Selection of Acid Types to Achieve Uniform Stimulation in Long Laterals of Horizontal Wells
Selection of Acid Types to Achieve Uniform Stimulation in Long Laterals of Horizontal Wells
Abstract
Horizontal wells with long laterals are being used to develop low-permeability carbonate reservoirs in the world. After completion of a well, acidizing is u...
The Paquette Synthesis of Fomannosin
The Paquette Synthesis of Fomannosin
The compact sesquiterpene ( + )-fomannosin 3, isolated from the pathogenic fungus Fomes annonsus, presents an interesting set of challenges for the organic synthesis chemist, rangi...
Experimental Evaluation of Lactic Acid for Matrix Acidizing of Carbonates
Experimental Evaluation of Lactic Acid for Matrix Acidizing of Carbonates
Summary
To improve the efficiency of standard hydrochloric acid (HCl) stimulation treatments, many alternative acid systems have been developed to mitigate corrosion...
Alkene complexes
Alkene complexes
This chapter discusses alkene complexes. Alkene (olefin) complexes now exist of every transition metal and constitute one of the most important classes of coordination compounds. T...

