Benzothiophene Adsorptive Desulfurization onto trihexYl(tetradecyl)phosphonium Dicyanamide Ionic-Liquid-Modified Renewable Carbon: Kinetic, Equilibrium and UV Spectroscopy Investigations

The negative environmental and industrial impacts of the presence of sulfur compounds such as benzothiophene in fuels have led to a greater interest in desulfurization research. In this work, carbon from palm waste sources was modified with trihexYl(tetradecyl)phosphonium dicyanamide-ionic liquid and characterized by SEM, EDS, XRD and FTIR to assess surface properties. Then, the prepared carbon and carbon modified with ionic liquid were evaluated for the adsorption of benzothiophene by investigating the effects of time. The equilibrium occurred after 120 min, recording adsorption capacities of 192 and 238 mg/g for carbon and carbon modified with ionic liquid, respectively. The effect of the adsorbent dose on the adsorption of benzothiophene was evaluated, indicating that the maximum adsorption capacities were obtained using a dose of 1 g/L for both carbon and carbon modified with ionic liquid. The kinetic investigation for the adsorption of benzothiophene onto carbon and carbon modified with ionic liquid indicated that the second-order kinetic model is well fitted with the adsorption data rather than the first-order kinetic model. The equilibrium investigations for the adsorption of benzothiophene onto carbon and carbon modified with ionic liquid with Langmuir and Freundlich isotherm models reveals that the Freundlich model is the most suitable for describing the adsorption process, suggesting a multilayer adsorption mechanism. The desulfurization process showed a high impact on environmental safety due to the possibility of regenerating and reusing the prepared adsorbents with promising results up to five cycles.