Search engine for discovering works of Art, research articles, and books related to Art and Culture
Javascript must be enabled to continue!
Recent advances in enantioselective reactions of terminal unactivated alkenes
View through CrossRef
α-Olefins as aliphatic terminal alkenes could be obtained easily from
numerous contemporary synthetic reactions as well as petrochemical
industry, and also found in natural products. Compared to the alkenes
attaching the directing groups or activating group, the catalytic
asymmetric reaction of unactivated terminal alkenes presents great
challenges due to the weak electron effect and small steric hindrance
effect. This review mainly summerizes the latest progress of the
asymmetric reaction of unactivated terminal olefins since 2016.
Title: Recent advances in enantioselective reactions of terminal unactivated alkenes
Description:
α-Olefins as aliphatic terminal alkenes could be obtained easily from
numerous contemporary synthetic reactions as well as petrochemical
industry, and also found in natural products.
Compared to the alkenes
attaching the directing groups or activating group, the catalytic
asymmetric reaction of unactivated terminal alkenes presents great
challenges due to the weak electron effect and small steric hindrance
effect.
This review mainly summerizes the latest progress of the
asymmetric reaction of unactivated terminal olefins since 2016.
Related Results
Calcium Hydride Cation Dimer Catalyzed Hydrogenation of Unactivated 1‐Alkenes and H2 Isotope Exchange: Competitive Ca−H−Ca Bridges and Terminal Ca−H Bonds
Calcium Hydride Cation Dimer Catalyzed Hydrogenation of Unactivated 1‐Alkenes and H2 Isotope Exchange: Competitive Ca−H−Ca Bridges and Terminal Ca−H Bonds
AbstractRecently, it was shown that the double Ca−H−Ca bridged calcium hydride cation dimer complex [LCaH2CaL]2+ (macrocyclic ligand L=NNNN‐tetradentate Me4TACD) exhibited remarkab...
The Need to Factor Asset Risk Into LNG Terminal Agreement Negotiations
The Need to Factor Asset Risk Into LNG Terminal Agreement Negotiations
Abstract
As developers race around the globe building liquefied natural gas ("LNG") terminals, companies acquiring capacity at those terminals are analyzing their...
Merging Photoexcited Nitroarenes with Lewis Acid Catalysis for the Anaerobic Oxidation of Alkenes
Merging Photoexcited Nitroarenes with Lewis Acid Catalysis for the Anaerobic Oxidation of Alkenes
A protocol for the oxidation of alkenes to carbonyls and acetonides via the interplay of photoexcited nitroarenes and Lewis acid catalysis is described. Terminal 1,1-disubstitued a...
Palladium/Xu-Phos Catalyzed Enantioselective Intramolecular Heck Reaction of Unactivated Alkenes
Palladium/Xu-Phos Catalyzed Enantioselective Intramolecular Heck Reaction of Unactivated Alkenes
A highly enantioselective palladium-catalyzed intramolecular Heck
reaction of unactivated alkenes is developed, which provides a powerful
route to access a broad range of chiral
3,...
The Hydroformylation Reaction
The Hydroformylation Reaction
AbstractThe reaction of 1‐alkenes with carbon monoxide and hydrogen in the presence of a catalyst gives the corresponding homologous aldehydes. The discovery of this reaction was m...
Alih Kode Dan Campur Kode Dalam Interaksi Masyarakat Terminal Motabuik Kota Atambua
Alih Kode Dan Campur Kode Dalam Interaksi Masyarakat Terminal Motabuik Kota Atambua
This research aims to describe the use of language in community interactions at the Motabuik terminal, Atambua City. The use of language in question is the form and function of cod...
47.1.2.1.6 Alkyl-Mizoroki–Heck-Type Reactions
47.1.2.1.6 Alkyl-Mizoroki–Heck-Type Reactions
AbstractSubstituted alkenes are basic structural motifs in a large number of organic molecules and their synthesis has received continuous attention from synthetic chemists. One of...
Bamford‐Stevens Reaction
Bamford‐Stevens Reaction
Abstract
This reaction is the transformation of ketones and aldehydes into alkenes through the base‐promoted thermal or photolytic decomposition of
...