Colossal magnetoresistance in spinel type Zn1−xNixFe2O4

Spinel-type ferrites are widely used in practical applications. A fascinating property of Zn-Ni ferrites which reveals a direction for application is reported. A large negative magnetoresistance effect has been observed in ZnFe2O4 and Ni substituted Zn1−xNixFe2O4 ferrites of spinel structure. These materials are either ferrimagnetic or paramagnetic at room temperature and a spin (cluster) glass transition was found for some compositions at low temperatures. The magnetoresistance is either parabolic or linear with respect to applied field up to 9 T depending on the compositions and temperatures. It was found that the magnetoresistance effect increases as the Ni content increases in Zn1−xNixFe2O4 up to x=0.2 and then again decreases and finally become negligible for x=1.0, i.e., NiFe2O4. This magnetoresistance effect can be explained with the help of spin-dependent scattering and the Yafet-Kittel angle of the Ni-substituted Zn-Ni ferrites.