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Oxidation of difluorocarbene and subsequent trifluoromethoxylation
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AbstractAs a versatile intermediate, difluorocarbene is an electron-deficient transient species, meaning that its oxidation would be challenging. Herein we show that the oxidation of difluorocarbene could occur smoothly to generate carbonyl fluoride. The oxidation process is confirmed by successful trifluoromethoxylation,18O-trifluoromethoxylation, the observation of AgOCF3species, and DFT calculations.
Springer Science and Business Media LLC
Title: Oxidation of difluorocarbene and subsequent trifluoromethoxylation
Description:
AbstractAs a versatile intermediate, difluorocarbene is an electron-deficient transient species, meaning that its oxidation would be challenging.
Herein we show that the oxidation of difluorocarbene could occur smoothly to generate carbonyl fluoride.
The oxidation process is confirmed by successful trifluoromethoxylation,18O-trifluoromethoxylation, the observation of AgOCF3species, and DFT calculations.
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