Javascript must be enabled to continue!
Metallocenes
View through CrossRef
Abstract
Metallocenes are organometallic sandwich complexes that have been used in or investigated for multiple application fields, such as chemical intermediates, antiknock additives to gasoline, lubricants or anti‐cancer agents. The main application of metallocenes, however, is the use as catalysts during plastic production. Due to the widespread applications and increasing plastic production interest increased on potential health effects induced by metallocenes. The chapter describes commonly used metallocenes and summarizes available toxicological data and assessments.
Title: Metallocenes
Description:
Abstract
Metallocenes are organometallic sandwich complexes that have been used in or investigated for multiple application fields, such as chemical intermediates, antiknock additives to gasoline, lubricants or anti‐cancer agents.
The main application of metallocenes, however, is the use as catalysts during plastic production.
Due to the widespread applications and increasing plastic production interest increased on potential health effects induced by metallocenes.
The chapter describes commonly used metallocenes and summarizes available toxicological data and assessments.
Related Results
Arene complexes
Arene complexes
This chapter assesses arene complexes. Following the recognition in the early 1950s of the sandwich bonding principle for metallocenes, the existence of related sandwich complexes ...
Cyclopentadienyl complexes
Cyclopentadienyl complexes
This chapter evaluates cyclopentadienyl complexes. In 1948, Miller, Tebboth, and Tremaine, attempting to synthesize amines from olefins and nitrogen in the presence of iron catalys...
Polar Metallocenes
Polar Metallocenes
Crystalline polar metallocenes are potentially useful active materials as piezoelectrics, ferroelectrics, and multiferroics. Within density functional theory (DFT), we computed str...
Titanium: Organometallic Chemistry
Titanium: Organometallic Chemistry
AbstractThe majority of titanium organometallic chemistry involves complexes in which the titanium is in its highest oxidation state (+4) with cyclopentadienyl derivatives as ancil...
Ziegler‐Natta Polymerization
Ziegler‐Natta Polymerization
AbstractThis reaction involves a Lewis acid of an early transition metal (e.g., Ti, Zr, V, etc.) to catalyze the polymerization of vinyl monomers in the presence of trialkylaluminu...
Synthesis and Characterization of Cerium(IV) Metallocenes
Synthesis and Characterization of Cerium(IV) Metallocenes
By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate tw...
Advanced Macromolecular Architectures via Inorganic Polymers
Advanced Macromolecular Architectures via Inorganic Polymers
ABSTRACT
Advanced macromolecular architectures, extending beyond mere chemical composition, are key to unlocking new functionalities in inorganic polymers. This r...

