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Crystal Structure of trans-Bis[2-(p-fluorophenyl)-2-oxazolinek1N] platinum(II) dichloride]
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The title material was synthesised by the treatment of PtCl2 with 2-(4′-fluorophenyl)-2-oxazoline in a MeOH solution. The crystal system is monoclinic (space group P21/n; Z = 2); the unit-cell dimensions are a = 7.7152(7)Å, b = 11.517(1)Å, c = 11.168(1)Å with β = 110.123(2)°; V = 931.8(2)Å3). The final R value was 0.0149 (2030 observed reflections: I > 2σ(I)). The Pt atom coordinates with two N-bound oxazolines in addition to two (transoidally disposed) chloride atoms; these interactions result in a square planar geometry around the metal center.
Title: Crystal Structure of trans-Bis[2-(p-fluorophenyl)-2-oxazolinek1N] platinum(II) dichloride]
Description:
The title material was synthesised by the treatment of PtCl2 with 2-(4′-fluorophenyl)-2-oxazoline in a MeOH solution.
The crystal system is monoclinic (space group P21/n; Z = 2); the unit-cell dimensions are a = 7.
7152(7)Å, b = 11.
517(1)Å, c = 11.
168(1)Å with β = 110.
123(2)°; V = 931.
8(2)Å3).
The final R value was 0.
0149 (2030 observed reflections: I > 2σ(I)).
The Pt atom coordinates with two N-bound oxazolines in addition to two (transoidally disposed) chloride atoms; these interactions result in a square planar geometry around the metal center.
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