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Nonionic Tenside Ligands and its Application in Biphasic Catalysis
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Abstract
This review article mainly surveys our research results of biphasic catalysis with nonionic tenside ligands. Emphasis is given to the synthesis and property of cloud point of the nonionic tenside ligands, the general principles of thermoregulated phase-transfer catalysis (TRPTC) and thermoregulated phase-separable catalysis (TPSC). It also explores the applications of TRPTC and TPSC in the hydroformylation of higher olefins and CO selective reduction of nitroarenes. The introduction of TRPTC to biphasic systemis free from the shortcomings of classical aqueous/organic two-phase catalysis, in which the application scope is restrained by the water solubility of the organic substrate. The biphasic catalysis with nonionic tenside ligands was characterized by homogeneous catalysis coupled with convenient biphasic separation.
Title: Nonionic Tenside Ligands and its Application in Biphasic Catalysis
Description:
Abstract
This review article mainly surveys our research results of biphasic catalysis with nonionic tenside ligands.
Emphasis is given to the synthesis and property of cloud point of the nonionic tenside ligands, the general principles of thermoregulated phase-transfer catalysis (TRPTC) and thermoregulated phase-separable catalysis (TPSC).
It also explores the applications of TRPTC and TPSC in the hydroformylation of higher olefins and CO selective reduction of nitroarenes.
The introduction of TRPTC to biphasic systemis free from the shortcomings of classical aqueous/organic two-phase catalysis, in which the application scope is restrained by the water solubility of the organic substrate.
The biphasic catalysis with nonionic tenside ligands was characterized by homogeneous catalysis coupled with convenient biphasic separation.
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