Manganese Accumulation in Rock Varnish on a Desert Piedmont, Mojave Desert, California, and Application to Evaluating Varnish Development

AbstractRock varnish coatings tend to become thicker, darker, and more continuous over time, leading to the use of changes in overall varnish color and the percentage of clast surfaces covered by varnish as relative-age indicators. Manganese is the most characteristic element of subaerial rock varnishes, and the progressive development of varnish coats can be quantified by measuring the amount of Mn accumulated on a given area of rock surface. Manganese oxides were dissolved off varnished clasts collected from alluvial surfaces on the Soda Mountains piedmont in the Mojave Desert, California, and the amount of Mn was measured using inductively coupled plasma emission spectroscopy. On the distal piedmont, maximum varnish development increases from a mid- to late-Holocene surface, typically containing up to 0.15 mg/cm2 of accumulated Mn, to an early- to mid-Holocene surface with up to 0.21 mg/cm2. However, varnish is less developed on a nearby late Pleistocene surface, suggesting extensive abrasion of clasts on the Pleistocene desert pavements or disturbance of the clasts. Varnish is better developed on the proximal piedmont, typically containing up to 0.30 mg/cm2 of Mn, although varnish from a Pleistocene surface is again no better developed than from a nearby early- to mid-Holocene surface. These data demonstrate that rock varnish can show significant spatial variation in degree of development on geomorphic surfaces of similar age, and imply that collecting varnish as old as a geomorphic surface may be difficult on surfaces as young as late Pleistocene.