Search engine for discovering works of Art, research articles, and books related to Art and Culture
Javascript must be enabled to continue!
Transition Metal- and Oxidant-Free Base-Mediated Selenation of Bicyclic Arenes at Room Temperature
View through CrossRef
Abstract
Bicyclic arenyl selenides are of much importance because of their pharmaceutical applications. A simple method for their synthesis has been developed by a reaction of 2-naphthol and styrenyl selenocyanate/diaryl diselenide in the presence of a base at room temperature. The selenation occurs exclusively at the 1-position of 2-naphthol unit. The reactions are relatively fast (2–4 h) and high yielding. A library of substituted naphthyl styrenyl and naphthyl aryl selenides are obtained by this procedure.
Title: Transition Metal- and Oxidant-Free Base-Mediated Selenation
of Bicyclic Arenes at Room Temperature
Description:
Abstract
Bicyclic arenyl selenides are of much importance because of their pharmaceutical applications.
A simple method for their synthesis has been developed by a reaction of 2-naphthol and styrenyl selenocyanate/diaryl diselenide in the presence of a base at room temperature.
The selenation occurs exclusively at the 1-position of 2-naphthol unit.
The reactions are relatively fast (2–4 h) and high yielding.
A library of substituted naphthyl styrenyl and naphthyl aryl selenides are obtained by this procedure.
Related Results
Environmental Surveillance Protocols for Highly Pathogenic Avian Influenza (HPAI) v2
Environmental Surveillance Protocols for Highly Pathogenic Avian Influenza (HPAI) v2
EnvironmentalSurveillance Protocols for Highly Pathogenic Avian Influenza (HPAI) This comprehensive protocol suite enables systematic environmental surveillance for avian influenza...
Bio-based polyesters from cyclic monomers derived from carbohydrates
Bio-based polyesters from cyclic monomers derived from carbohydrates
Polyesters are extremely versatile polymers which can be used in a wide variety of applications ranging from high performance materials to recyclable and degradable polymers. The p...
Accessing diverse bicyclic peptide conformations using 1,2,3-TBMB as a linker
Accessing diverse bicyclic peptide conformations using 1,2,3-TBMB as a linker
Bicyclic peptides are a powerful modality for the engagement of challenging drug targets such as protein-protein interactions. The most common crosslinkers used to generate bicycli...
Computer-Mediated Chat
Computer-Mediated Chat
The technical apparatus is, then, being made at home with the rest of our world. And that's a thing that's routinely being done, and it's the source of the failure of technocratic ...
Fertility Transition Across Major Sub-Saharan African Cities: The Role of Proximate Determinants
Fertility Transition Across Major Sub-Saharan African Cities: The Role of Proximate Determinants
Abstract
Background
Sub-Saharan Africa’s fertility transition has lagged behind other regions despite rapid urbanization, resulting in persistently high fertility rates. S...
Kinetics and Mechanisms of Metal Carbonyls
Kinetics and Mechanisms of Metal Carbonyls
Pulsed laser flash photolysis with both visible and infrared detection has been applied to the study of the displacement of weakly coordinating ligands (Lw) by strongly "trapping" ...
Bicyclic Sultams: From Organic Chemistry to Pharmaceutical Science
Bicyclic Sultams: From Organic Chemistry to Pharmaceutical Science
AbstractCyclic sulfonamides (sultams) widely distributed in pharmaceuticals due to their abundant biological activities. Currently, many pharmaceuticals with bicyclic sultam scaffo...
Fluorescent Macrocyclic Arenes: Synthesis and Applications
Fluorescent Macrocyclic Arenes: Synthesis and Applications
AbstractFluorescent macrocyclic arenes have attracted increasing interest in macrocyclic and supramolecular chemistry due to their exceptional photophysical properties and versatil...