A Review of Rubber Biocomposites Reinforced with Lignocellulosic Fillers

Lignocellulosic fillers have attracted considerable attention over the years as a promising alternative to conventional petroleum-based fillers (carbon black) in rubber composites due to their renewability, biodegradability, availability, high mechanical properties, low density and low cost. Based on the literature available, a comprehensive review is presented here of rubber biocomposites reinforced with plant-based fillers. The study is divided into different sections depending on the matrix (natural or synthetic rubber) and the type of lignocellulosic fillers (natural fiber, microcrystalline cellulose, lignin and nanocellulose). This review focuses on the curing characteristics, mechanical properties and dynamic mechanical properties of the resulting rubber biocomposites. In addition, the effect of hybrid filler systems, lignocellulosic filler surface modification and modification of the rubber matrix on the properties of these rubber biocomposites are presented and compared. A conclusion is finally presented with some openings for future works.