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Diferrocenyl(methylthio)cyclopropenylium Iodide in the Synthesis of2,3‐Diferrocenyl‐1‐methylthio‐1,3‐dienes and ‐1,3,5‐trienes
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AbstractDiferrocenyl(methylthio)cyclopropenylium iodide reacts with organometallic compounds (methyllithium, benzyl‐ and ethylmagnesium chlorides, and allylmagnesium bromide) to yield 2,3‐diferrocenyl‐1‐methylthio‐1,3‐dienes or ‐1,3,5‐triene together with 3,3‐dialkyl‐1,2‐diferrocenylcyclopropenes. We present data from X‐ray diffraction analyses of (E)‐2,3‐diferrocenyl‐1‐methylthio‐ and (E,Z)‐2,3‐diferrocenyl‐1‐methylthio‐4‐phenyl‐1,3‐butadienes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Title: Diferrocenyl(methylthio)cyclopropenylium Iodide in the Synthesis of2,3‐Diferrocenyl‐1‐methylthio‐1,3‐dienes and ‐1,3,5‐trienes
Description:
AbstractDiferrocenyl(methylthio)cyclopropenylium iodide reacts with organometallic compounds (methyllithium, benzyl‐ and ethylmagnesium chlorides, and allylmagnesium bromide) to yield 2,3‐diferrocenyl‐1‐methylthio‐1,3‐dienes or ‐1,3,5‐triene together with 3,3‐dialkyl‐1,2‐diferrocenylcyclopropenes.
We present data from X‐ray diffraction analyses of (E)‐2,3‐diferrocenyl‐1‐methylthio‐ and (E,Z)‐2,3‐diferrocenyl‐1‐methylthio‐4‐phenyl‐1,3‐butadienes.
(© Wiley‐VCH Verlag GmbH & Co.
KGaA, 69451 Weinheim, Germany, 2005).
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