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Synthesis of 2-Aminomethyloxiranes
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Abstract
Several 2-aminomethyloxiranes (2) have been synthesized in good yields by the reaction of 2-(1-bromoalkyl)oxiranes (1) with primary or secondary amines. cis-2-Aminomethyloxiranes (2) were obtained from syn-(2-bromomethyl)oxiranes (1) with amines and KOH, and trans-2-aminomethyloxiranes (2) were obtained from anti-(2-bromomethyl)oxiranes (1) with amines, respectively, with stereospecific manner.
Title: Synthesis of 2-Aminomethyloxiranes
Description:
Abstract
Several 2-aminomethyloxiranes (2) have been synthesized in good yields by the reaction of 2-(1-bromoalkyl)oxiranes (1) with primary or secondary amines.
cis-2-Aminomethyloxiranes (2) were obtained from syn-(2-bromomethyl)oxiranes (1) with amines and KOH, and trans-2-aminomethyloxiranes (2) were obtained from anti-(2-bromomethyl)oxiranes (1) with amines, respectively, with stereospecific manner.
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