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Determination of submillimolar concentration of ferrate(VI) in alkaline solutions by amperometric titration

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Abstract A new amperometric titration method was developed for quantitative determination of ferrate(VI) (FeVIO42−) in the 7.06×10−5−5.73×10−3 M concentration range. Chromium(III) hydroxide solution was used as the titrant. The diffusion current (Id) had a linear relationship with the concentration of ferrate(VI) and slopes were dependent on the concentration of NaOH. The amperometric titration could detect a lower concentration of ferrate(VI) than could potentiometric and colorimetric titrations. The method was applied successfully to determine concentrations of ferrate(VI), generated electrochemically, in strong alkaline solutions.
Title: Determination of submillimolar concentration of ferrate(VI) in alkaline solutions by amperometric titration
Description:
Abstract A new amperometric titration method was developed for quantitative determination of ferrate(VI) (FeVIO42−) in the 7.
06×10−5−5.
73×10−3 M concentration range.
Chromium(III) hydroxide solution was used as the titrant.
The diffusion current (Id) had a linear relationship with the concentration of ferrate(VI) and slopes were dependent on the concentration of NaOH.
The amperometric titration could detect a lower concentration of ferrate(VI) than could potentiometric and colorimetric titrations.
The method was applied successfully to determine concentrations of ferrate(VI), generated electrochemically, in strong alkaline solutions.

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