Javascript must be enabled to continue!
Synthesis of propargyl(allyl) aryloxyethers
View through CrossRef
A convenient method for the synthesis of propargyl(allyl) aryloxyethers is proposed. It is notable that the synthesized compounds exhibit increased reactivity and are rich in nucleophilic centers. Experimental data have established that these compounds are stable and do not undergo hydrolysis. The yields of the target products in both cases are up to 89.2%. The reaction duration and the volume of substituents at the alkoxy group do not significantly affect the yield of the target products. The composition of the synthesized compounds includes groups of signals from protons of the allyl and propargyl groups. The reactions and purity of the obtained compounds were monitored by thin layer chromatography. The yields of allyl ethers are higher than those of propargyl ethers. Some physicochemical properties of the synthesized compounds are presented, and their composition and structure are confirmed by elemental analysis. All synthesized compounds have been identified by IR and NMR spectroscopy.
SHEI Ukrainian State University of Chemical Technology
Title: Synthesis of propargyl(allyl) aryloxyethers
Description:
A convenient method for the synthesis of propargyl(allyl) aryloxyethers is proposed.
It is notable that the synthesized compounds exhibit increased reactivity and are rich in nucleophilic centers.
Experimental data have established that these compounds are stable and do not undergo hydrolysis.
The yields of the target products in both cases are up to 89.
2%.
The reaction duration and the volume of substituents at the alkoxy group do not significantly affect the yield of the target products.
The composition of the synthesized compounds includes groups of signals from protons of the allyl and propargyl groups.
The reactions and purity of the obtained compounds were monitored by thin layer chromatography.
The yields of allyl ethers are higher than those of propargyl ethers.
Some physicochemical properties of the synthesized compounds are presented, and their composition and structure are confirmed by elemental analysis.
All synthesized compounds have been identified by IR and NMR spectroscopy.
Related Results
Tsuji‐Trost Reaction
Tsuji‐Trost Reaction
Abstract
The mild synthesis of allylic compounds via palladium catalyzed allylic alkylation of activated nucleophiles is generally known as the Tsuji–Trost r...
Nickel-Catalyzed Cross-Electrophile aryl–allyl Coupling: An Approach to Structurally Versatile Allyl substituted arylborate
Nickel-Catalyzed Cross-Electrophile aryl–allyl Coupling: An Approach to Structurally Versatile Allyl substituted arylborate
The synthesis of allyl-substituted functional aryl compounds is one of the challenges existing in organic chemistry. Herein, we report a method for constructing allyl-substituted a...
Effect of nano-urea and herbicides on yield and yield attributes of wheat (Triticum aestivum)
Effect of nano-urea and herbicides on yield and yield attributes of wheat (Triticum aestivum)
A field experiment was conducted during the winter (rabi) season of 2021–22 at Indian Agricultural Research Institute, New Delhi, to investigate the effect of nano-urea and herbici...
Herbicidal weed management in groundnut (Arachis hypogaea) and its residual effect on succeeding wheat (Triticum aestivum) crop
Herbicidal weed management in groundnut (Arachis hypogaea) and its residual effect on succeeding wheat (Triticum aestivum) crop
A field experiment was carried out at Mandore, Jodhpur, Rajasthan, during the rainy (kharif) and winter (rabi) seasons of 201718 and 201819, to study the herbicidal weed management...
Ability of Aspergillus flavus to degradation of herbicide Topik EC 100 (Clodinafop-propargyl)
Ability of Aspergillus flavus to degradation of herbicide Topik EC 100 (Clodinafop-propargyl)
Aspergillus flavus was isolated from the soil field cultivated with wheat crop (Triticum astevium L.), which was treated with Topik EC 100 (Clodinafop-propargyl) herbicide in Al-Fu...
Ability of Aspergillus niger to degradation of herbicide Topik EC100 (Clodinafop-propargyl)
Ability of Aspergillus niger to degradation of herbicide Topik EC100 (Clodinafop-propargyl)
Aspergillus niger was isolated from the soil field cultivated with wheat crop (Triticum astevium L.), which was treated with Topik EC 100 (Clodinafop-propargyl) herbicide in Al-Fuh...
Isolation, characterization and semi-synthesis of natural products dimeric amide alkaloids
Isolation, characterization and semi-synthesis of natural products dimeric amide alkaloids
Isolation, characterization of natural products dimeric amide alkaloids from roots of the Piper chaba Hunter. The synthesis of these products using intermolecular [4+2] cycloaddit...
ChemInform Abstract: A Stereospecific Synthesis of Optically Active Allylsilanes.
ChemInform Abstract: A Stereospecific Synthesis of Optically Active Allylsilanes.
AbstractThe optically active propargyl alcohol (I) is converted into the allyl silanes (IV) and (VII) via the allyl benzoate (II) and allyl urethane (VI)....

