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Radiolysis of Trifluoroacetic Acid
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The gaseous products of the 60Co-γ radiolysis of liquid CF3COOH at 23 °C and solid CF3COOH at −196 °C have been identified and their G-values have been determined. The products and G-values are, for the radiolysis of liquid CF3COOH; CO2(7.1), CO(0.71), CF3H(0.27), C2F6(1.36), H2(0.031) and, for the radiolysis of solid CF3COOH; CO2(2.5), CF3H(0.30), C2F6(0.39). CO and H2 are not produced in the radiolysis of solid CF3COOH and CF4 and C2F4 are not produced in the radiolysis of solid and liquid CF3COOH. The mechanisms of gaseous product formation in the radiolysis of solid and liquid CF3COOH are compared.
Title: Radiolysis of Trifluoroacetic Acid
Description:
The gaseous products of the 60Co-γ radiolysis of liquid CF3COOH at 23 °C and solid CF3COOH at −196 °C have been identified and their G-values have been determined.
The products and G-values are, for the radiolysis of liquid CF3COOH; CO2(7.
1), CO(0.
71), CF3H(0.
27), C2F6(1.
36), H2(0.
031) and, for the radiolysis of solid CF3COOH; CO2(2.
5), CF3H(0.
30), C2F6(0.
39).
CO and H2 are not produced in the radiolysis of solid CF3COOH and CF4 and C2F4 are not produced in the radiolysis of solid and liquid CF3COOH.
The mechanisms of gaseous product formation in the radiolysis of solid and liquid CF3COOH are compared.
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