Electrochemistry of the Iron Group

Title: Electrochemistry of the Iron Group

Description:

AbstractThe sections in this article areIntroductionElectrochemistry of Low‐valent Iron Complexes (Iron −IIto +II)Iron(−II): Collman's Reagent via Reduction of Iron(0) PentacarbonylBridged Di‐iron CarbonylsThe [Fe2(CO)8]2−/1−SystemPhosphido Bridged Iron CarbonylsThiolate‐bridged Iron Carbonyl: Cathodic Electrochemical BehaviorThiolate‐bridged Iron Carbonyls: Simple Dinuclear Models for the Active Center of the Iron‐only HydrogenaseLow‐valent Iron PorphyrinsCatalysis of Electrochemical Hydrogen EvolutionCatalysis of Electrochemical Carbon Dioxide ReductionStabilization of Low Iron Oxidation State by Interlocked Macrocyclic LigandsStable Low‐valent Iron Arene‐cyclopentadienyl Species: Strong Organometallic ReductantsConclusions on Low‐valent Iron SystemsMid‐valent Iron Complexes' Electrochemistry (IronIIandIII)Ferrocene and Related ComplexesFilling the Electrochemical Window with FerrocenylsChoosing the Adequate Internal ReferenceSensing with FerrocenylsMediating Electron Transfer Between an Enzyme and an ElectrodeCoordination Complexes and Bioelectrochemical ApplicationsLigand Types and Electrochemical PropertiesBipyridine and Phenanthroline Complexes of the Iron Group and Biolelectrochemical ApplicationsSwitching Mechanisms Involving Translocation of IronSimple Iron Complexes: Hexa‐aqua Iron, Ferri‐ferro Cyanide, and Tetrachloro FerrateConclusion on Mid‐valent Iron SystemsHigh‐valent Iron Complexes' Electrochemistry (IronIIIto IronVI)IntroductionSelected Examples of High‐valent Iron Complexes' ElectrochemistryConclusions on High‐valent Iron SystemsConclusions.